TY - JOUR
T1 - 3(1,3-Heterazolidin-3-yl-methyl)-1,3-oxazolidines and their reduction with borane-THF
AU - Salas-Coronado, Raúl
AU - Gálvez-Ruíz, Juan Carlos
AU - Jaen-Gaspar, Javier C.
AU - Nöth, Heinrich
AU - Flores-Parra, Angelina
PY - 2003/11/17
Y1 - 2003/11/17
N2 - Preparation of bis-heterazolidines bonded by a CH2, CH2-S-CH2or CH2SCH2SCH2groups through their nitrogen atoms is reported: 3-(1,3-oxazolidin-3-ylmethyl)- 1,3-oxazolidine 1, 3-(4,4-dimethyl-1,3-oxazolidin-3-ylmethyl)-1,3-oxazolidine 2, 3-(1,3-diazolidin-3-ylmethyl)-1,3-diazolidine 3, 3-(1,3-thiazolidin-3-ylmethyl) -1,3-thiazolidine 4, 3-(1,3-thiazolidin-3-ylmethylsulfanylmethyl)-1,3- thiazolidine 5 and 3-(1,3-oxazolidin-3-ylmethylsulfanylmethyl-sulfanylmethyl)-1, 3-oxazolidine 6. The solid state structures of 4 and 5 were determined by X-ray diffraction analyses. BH3-THF reduction reactions of compounds 1-6 were investigated. N→BH3mono- and di-adducts of 1-6 were prepared and their structures calculated (ab initio 3-21G*). © 2003 Elsevier B.V. All rights reserved.
AB - Preparation of bis-heterazolidines bonded by a CH2, CH2-S-CH2or CH2SCH2SCH2groups through their nitrogen atoms is reported: 3-(1,3-oxazolidin-3-ylmethyl)- 1,3-oxazolidine 1, 3-(4,4-dimethyl-1,3-oxazolidin-3-ylmethyl)-1,3-oxazolidine 2, 3-(1,3-diazolidin-3-ylmethyl)-1,3-diazolidine 3, 3-(1,3-thiazolidin-3-ylmethyl) -1,3-thiazolidine 4, 3-(1,3-thiazolidin-3-ylmethylsulfanylmethyl)-1,3- thiazolidine 5 and 3-(1,3-oxazolidin-3-ylmethylsulfanylmethyl-sulfanylmethyl)-1, 3-oxazolidine 6. The solid state structures of 4 and 5 were determined by X-ray diffraction analyses. BH3-THF reduction reactions of compounds 1-6 were investigated. N→BH3mono- and di-adducts of 1-6 were prepared and their structures calculated (ab initio 3-21G*). © 2003 Elsevier B.V. All rights reserved.
U2 - 10.1016/j.theochem.2003.08.067
DO - 10.1016/j.theochem.2003.08.067
M3 - Article
SP - 95
EP - 108
JO - Journal of Molecular Structure: THEOCHEM
JF - Journal of Molecular Structure: THEOCHEM
SN - 0166-1280
ER -