3(1,3-Heterazolidin-3-yl-methyl)-1,3-oxazolidines and their reduction with borane-THF

Raúl Salas-Coronado; Juan Carlos Gálvez-Ruíz; Javier C. Jaen-Gaspar; Heinrich Nöth; Angelina Flores-Parra

doi:10.1016/j.theochem.2003.08.067

3(1,3-Heterazolidin-3-yl-methyl)-1,3-oxazolidines and their reduction with borane-THF

Raúl Salas-Coronado, Juan Carlos Gálvez-Ruíz, Javier C. Jaen-Gaspar, Heinrich Nöth, Angelina Flores-Parra^*

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

Preparation of bis-heterazolidines bonded by a CH₂, CH ₂-S-CH₂ or CH₂SCH₂SCH₂ groups through their nitrogen atoms is reported: 3-(1,3-oxazolidin-3-ylmethyl)- 1,3-oxazolidine 1, 3-(4,4-dimethyl-1,3-oxazolidin-3-ylmethyl)-1,3-oxazolidine 2, 3-(1,3-diazolidin-3-ylmethyl)-1,3-diazolidine 3, 3-(1,3-thiazolidin-3-ylmethyl) -1,3-thiazolidine 4, 3-(1,3-thiazolidin-3-ylmethylsulfanylmethyl)-1,3- thiazolidine 5 and 3-(1,3-oxazolidin-3-ylmethylsulfanylmethyl-sulfanylmethyl)-1, 3-oxazolidine 6. The solid state structures of 4 and 5 were determined by X-ray diffraction analyses. BH₃-THF reduction reactions of compounds 1-6 were investigated. N→BH₃ mono- and di-adducts of 1-6 were prepared and their structures calculated (ab initio 3-21G*).

Original language	English
Pages (from-to)	95-108
Number of pages	14
Journal	Journal of Molecular Structure: THEOCHEM
Volume	640
Issue number	1-3
DOIs	https://doi.org/10.1016/j.theochem.2003.08.067
State	Published - 17 Nov 2003
Externally published	Yes

Keywords

3(1,3-Heterazolidin-3-yl-methyl)-1,3,-oxazolidines
N→BH adducts

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10.1016/j.theochem.2003.08.067

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title = "3(1,3-Heterazolidin-3-yl-methyl)-1,3-oxazolidines and their reduction with borane-THF",

abstract = "Preparation of bis-heterazolidines bonded by a CH2, CH 2-S-CH2 or CH2SCH2SCH2 groups through their nitrogen atoms is reported: 3-(1,3-oxazolidin-3-ylmethyl)- 1,3-oxazolidine 1, 3-(4,4-dimethyl-1,3-oxazolidin-3-ylmethyl)-1,3-oxazolidine 2, 3-(1,3-diazolidin-3-ylmethyl)-1,3-diazolidine 3, 3-(1,3-thiazolidin-3-ylmethyl) -1,3-thiazolidine 4, 3-(1,3-thiazolidin-3-ylmethylsulfanylmethyl)-1,3- thiazolidine 5 and 3-(1,3-oxazolidin-3-ylmethylsulfanylmethyl-sulfanylmethyl)-1, 3-oxazolidine 6. The solid state structures of 4 and 5 were determined by X-ray diffraction analyses. BH3-THF reduction reactions of compounds 1-6 were investigated. N→BH3 mono- and di-adducts of 1-6 were prepared and their structures calculated (ab initio 3-21G*).",

keywords = "3(1,3-Heterazolidin-3-yl-methyl)-1,3,-oxazolidines, N→BH adducts",

author = "Ra{\'u}l Salas-Coronado and G{\'a}lvez-Ru{\'i}z, {Juan Carlos} and Jaen-Gaspar, {Javier C.} and Heinrich N{\"o}th and Angelina Flores-Parra",

year = "2003",

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doi = "10.1016/j.theochem.2003.08.067",

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T1 - 3(1,3-Heterazolidin-3-yl-methyl)-1,3-oxazolidines and their reduction with borane-THF

AU - Salas-Coronado, Raúl

AU - Gálvez-Ruíz, Juan Carlos

AU - Jaen-Gaspar, Javier C.

AU - Nöth, Heinrich

AU - Flores-Parra, Angelina

PY - 2003/11/17

Y1 - 2003/11/17

N2 - Preparation of bis-heterazolidines bonded by a CH2, CH 2-S-CH2 or CH2SCH2SCH2 groups through their nitrogen atoms is reported: 3-(1,3-oxazolidin-3-ylmethyl)- 1,3-oxazolidine 1, 3-(4,4-dimethyl-1,3-oxazolidin-3-ylmethyl)-1,3-oxazolidine 2, 3-(1,3-diazolidin-3-ylmethyl)-1,3-diazolidine 3, 3-(1,3-thiazolidin-3-ylmethyl) -1,3-thiazolidine 4, 3-(1,3-thiazolidin-3-ylmethylsulfanylmethyl)-1,3- thiazolidine 5 and 3-(1,3-oxazolidin-3-ylmethylsulfanylmethyl-sulfanylmethyl)-1, 3-oxazolidine 6. The solid state structures of 4 and 5 were determined by X-ray diffraction analyses. BH3-THF reduction reactions of compounds 1-6 were investigated. N→BH3 mono- and di-adducts of 1-6 were prepared and their structures calculated (ab initio 3-21G*).

AB - Preparation of bis-heterazolidines bonded by a CH2, CH 2-S-CH2 or CH2SCH2SCH2 groups through their nitrogen atoms is reported: 3-(1,3-oxazolidin-3-ylmethyl)- 1,3-oxazolidine 1, 3-(4,4-dimethyl-1,3-oxazolidin-3-ylmethyl)-1,3-oxazolidine 2, 3-(1,3-diazolidin-3-ylmethyl)-1,3-diazolidine 3, 3-(1,3-thiazolidin-3-ylmethyl) -1,3-thiazolidine 4, 3-(1,3-thiazolidin-3-ylmethylsulfanylmethyl)-1,3- thiazolidine 5 and 3-(1,3-oxazolidin-3-ylmethylsulfanylmethyl-sulfanylmethyl)-1, 3-oxazolidine 6. The solid state structures of 4 and 5 were determined by X-ray diffraction analyses. BH3-THF reduction reactions of compounds 1-6 were investigated. N→BH3 mono- and di-adducts of 1-6 were prepared and their structures calculated (ab initio 3-21G*).

KW - 3(1,3-Heterazolidin-3-yl-methyl)-1,3,-oxazolidines

KW - N→BH adducts

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U2 - 10.1016/j.theochem.2003.08.067

DO - 10.1016/j.theochem.2003.08.067

M3 - Artículo

SN - 0166-1280

VL - 640

SP - 95

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JO - Journal of Molecular Structure: THEOCHEM

JF - Journal of Molecular Structure: THEOCHEM

IS - 1-3

ER -

3(1,3-Heterazolidin-3-yl-methyl)-1,3-oxazolidines and their reduction with borane-THF

Abstract

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