3(1,3-Heterazolidin-3-yl-methyl)-1,3-oxazolidines and their reduction with borane-THF

Raúl Salas-Coronado, Juan Carlos Gálvez-Ruíz, Javier C. Jaen-Gaspar, Heinrich Nöth, Angelina Flores-Parra

Research output: Contribution to journalArticlepeer-review

2 Scopus citations


Preparation of bis-heterazolidines bonded by a CH2, CH2-S-CH2or CH2SCH2SCH2groups through their nitrogen atoms is reported: 3-(1,3-oxazolidin-3-ylmethyl)- 1,3-oxazolidine 1, 3-(4,4-dimethyl-1,3-oxazolidin-3-ylmethyl)-1,3-oxazolidine 2, 3-(1,3-diazolidin-3-ylmethyl)-1,3-diazolidine 3, 3-(1,3-thiazolidin-3-ylmethyl) -1,3-thiazolidine 4, 3-(1,3-thiazolidin-3-ylmethylsulfanylmethyl)-1,3- thiazolidine 5 and 3-(1,3-oxazolidin-3-ylmethylsulfanylmethyl-sulfanylmethyl)-1, 3-oxazolidine 6. The solid state structures of 4 and 5 were determined by X-ray diffraction analyses. BH3-THF reduction reactions of compounds 1-6 were investigated. N→BH3mono- and di-adducts of 1-6 were prepared and their structures calculated (ab initio 3-21G*). © 2003 Elsevier B.V. All rights reserved.
Original languageAmerican English
Pages (from-to)95-108
Number of pages14
JournalJournal of Molecular Structure: THEOCHEM
StatePublished - 17 Nov 2003
Externally publishedYes


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