Advances in Cross-Coupling Reactions Catalyzed by Aromatic Pincer Complexes Based on Earth-Abundant 3d Metals (Mn, Fe, Co, Ni, Cu)

Jesús Antonio Cruz-Navarro; Arturo Sánchez-Mora; Juan S. Serrano-García; Andrés Amaya-Flórez; Raúl Colorado-Peralta; Viviana Reyes-Márquez; David Morales-Morales

doi:10.3390/catal14010069

Advances in Cross-Coupling Reactions Catalyzed by Aromatic Pincer Complexes Based on Earth-Abundant 3d Metals (Mn, Fe, Co, Ni, Cu)

Jesús Antonio Cruz-Navarro^*, Arturo Sánchez-Mora, Juan S. Serrano-García, Andrés Amaya-Flórez, Raúl Colorado-Peralta, Viviana Reyes-Márquez, David Morales-Morales^*

^*Corresponding author for this work

Departamento de Ciencias Químico-Biológicas

Research output: Contribution to journal › Review article › peer-review

3 Scopus citations

Abstract

The increase of noble-metal-free catalysis in organic chemistry is a trending topic in constant growth due to the price increase of noble metals and their scarce abundance. As a result, many earth-abundant transition-metal complexes containing nickel, iron, or cobalt have been successfully applied in the homogeneous catalysis of a wide number of cross-coupling reactions, and the use of pincer complexes based on these earth-abundant metals was recently explored, affording interesting results. Thus, this review provides a general overview of earth-abundant 3D pincer complexes and their application during the last decade as catalysts in cross-coupling reactions such as Kumada–Corriu, Suzuki–Miyaura, Sonogashira, C–S cross-coupling, and C–N bond-forming reactions.

Original language	English
Article number	69
Journal	Catalysts
Volume	14
Issue number	1
DOIs	https://doi.org/10.3390/catal14010069
State	Published - Jan 2024

Bibliographical note

Publisher Copyright:
© 2024 by the authors.

Keywords

catalysis
cross-coupling reactions
earth-abundant transition metals
pincer complexes

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Cite this

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title = "Advances in Cross-Coupling Reactions Catalyzed by Aromatic Pincer Complexes Based on Earth-Abundant 3d Metals (Mn, Fe, Co, Ni, Cu)",

abstract = "The increase of noble-metal-free catalysis in organic chemistry is a trending topic in constant growth due to the price increase of noble metals and their scarce abundance. As a result, many earth-abundant transition-metal complexes containing nickel, iron, or cobalt have been successfully applied in the homogeneous catalysis of a wide number of cross-coupling reactions, and the use of pincer complexes based on these earth-abundant metals was recently explored, affording interesting results. Thus, this review provides a general overview of earth-abundant 3D pincer complexes and their application during the last decade as catalysts in cross-coupling reactions such as Kumada–Corriu, Suzuki–Miyaura, Sonogashira, C–S cross-coupling, and C–N bond-forming reactions.",

keywords = "catalysis, cross-coupling reactions, earth-abundant transition metals, pincer complexes",

author = "Cruz-Navarro, {Jes{\'u}s Antonio} and Arturo S{\'a}nchez-Mora and Serrano-Garc{\'i}a, {Juan S.} and Andr{\'e}s Amaya-Fl{\'o}rez and Ra{\'u}l Colorado-Peralta and Viviana Reyes-M{\'a}rquez and David Morales-Morales",

note = "Publisher Copyright: {\textcopyright} 2024 by the authors.",

year = "2024",

month = jan,

doi = "10.3390/catal14010069",

language = "Ingl{\'e}s",

volume = "14",

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T1 - Advances in Cross-Coupling Reactions Catalyzed by Aromatic Pincer Complexes Based on Earth-Abundant 3d Metals (Mn, Fe, Co, Ni, Cu)

AU - Cruz-Navarro, Jesús Antonio

AU - Sánchez-Mora, Arturo

AU - Serrano-García, Juan S.

AU - Amaya-Flórez, Andrés

AU - Colorado-Peralta, Raúl

AU - Reyes-Márquez, Viviana

AU - Morales-Morales, David

PY - 2024/1

Y1 - 2024/1

N2 - The increase of noble-metal-free catalysis in organic chemistry is a trending topic in constant growth due to the price increase of noble metals and their scarce abundance. As a result, many earth-abundant transition-metal complexes containing nickel, iron, or cobalt have been successfully applied in the homogeneous catalysis of a wide number of cross-coupling reactions, and the use of pincer complexes based on these earth-abundant metals was recently explored, affording interesting results. Thus, this review provides a general overview of earth-abundant 3D pincer complexes and their application during the last decade as catalysts in cross-coupling reactions such as Kumada–Corriu, Suzuki–Miyaura, Sonogashira, C–S cross-coupling, and C–N bond-forming reactions.

AB - The increase of noble-metal-free catalysis in organic chemistry is a trending topic in constant growth due to the price increase of noble metals and their scarce abundance. As a result, many earth-abundant transition-metal complexes containing nickel, iron, or cobalt have been successfully applied in the homogeneous catalysis of a wide number of cross-coupling reactions, and the use of pincer complexes based on these earth-abundant metals was recently explored, affording interesting results. Thus, this review provides a general overview of earth-abundant 3D pincer complexes and their application during the last decade as catalysts in cross-coupling reactions such as Kumada–Corriu, Suzuki–Miyaura, Sonogashira, C–S cross-coupling, and C–N bond-forming reactions.

KW - catalysis

KW - cross-coupling reactions

KW - earth-abundant transition metals

KW - pincer complexes

UR - http://www.scopus.com/inward/record.url?scp=85183345167&partnerID=8YFLogxK

U2 - 10.3390/catal14010069

DO - 10.3390/catal14010069

M3 - Artículo de revisión

AN - SCOPUS:85183345167

SN - 2073-4344

VL - 14

JO - Catalysts

JF - Catalysts

IS - 1

M1 - 69

ER -

Advances in Cross-Coupling Reactions Catalyzed by Aromatic Pincer Complexes Based on Earth-Abundant 3d Metals (Mn, Fe, Co, Ni, Cu)

Abstract

Bibliographical note

Keywords

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