Berry exchange coordinate geometry in 3-methyl-2-hydroxycyclopenten-1-one tin esters

Carlos Camacho-Camacho; Victor M. Jiménez-Pérez; Juan Carlos Galvez-Ruiz; Angelina Flores-Parra; Rosalinda Contreras

doi:10.1016/j.jorganchem.2005.12.036

Berry exchange coordinate geometry in 3-methyl-2-hydroxycyclopenten-1-one tin esters

Carlos Camacho-Camacho, Victor M. Jiménez-Pérez, Juan Carlos Galvez-Ruiz, Angelina Flores-Parra^*, Rosalinda Contreras

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Three new penta- and hexacoordinated tin compounds (1-3) were prepared from PhSnCl₃, Ph₂SnCl₂ and Ph₃SnOH and 3-methyl-2-hydroxy-2-cyclopenten-1-one (L). Compounds 1-3 were characterized by IR, mass spectra, elemental analysis, ¹H, ¹³C, and ¹¹⁹Sn NMR. The ligand acts as a bidentate giving the tin esters and coordinating the tin by the carbonyl group. Compound 1 (PhSnCl₂L • EtOH) has an hexacoordinated tin atom, with an octahedral distorted geometry, which is a stereogenic center. Compounds 2 (Ph₂SnClL) and 3 (Ph₃SnL) have pentacoordinated tin atoms. The structures were determined by X-ray diffraction analyses. In the solid state 1 presents a racemic pair, linked by strong hydrogen bonds and 2 and 3 "Berry exchange coordinate" geometry.

Original language	English
Pages (from-to)	1590-1597
Number of pages	8
Journal	Journal of Organometallic Chemistry
Volume	691
Issue number	8
DOIs	https://doi.org/10.1016/j.jorganchem.2005.12.036
State	Published - 1 Apr 2006
Externally published	Yes

Bibliographical note

Funding Information:
Financial support from Cinvestav, Conacyt and UAM-X is acknowledged.

Keywords

3-Methyl-2-hydroxycyclopenten-2-one tin compounds
Berry exchange coordinate geometry
Penta- and hexacoordinated tin derivatives

Access to Document

10.1016/j.jorganchem.2005.12.036

Cite this

@article{994d76f2d6c54f4fb30a762d7f1a8bc2,

title = "Berry exchange coordinate geometry in 3-methyl-2-hydroxycyclopenten-1-one tin esters",

abstract = "Three new penta- and hexacoordinated tin compounds (1-3) were prepared from PhSnCl3, Ph2SnCl2 and Ph3SnOH and 3-methyl-2-hydroxy-2-cyclopenten-1-one (L). Compounds 1-3 were characterized by IR, mass spectra, elemental analysis, 1H, 13C, and 119Sn NMR. The ligand acts as a bidentate giving the tin esters and coordinating the tin by the carbonyl group. Compound 1 (PhSnCl2L • EtOH) has an hexacoordinated tin atom, with an octahedral distorted geometry, which is a stereogenic center. Compounds 2 (Ph2SnClL) and 3 (Ph3SnL) have pentacoordinated tin atoms. The structures were determined by X-ray diffraction analyses. In the solid state 1 presents a racemic pair, linked by strong hydrogen bonds and 2 and 3 {"}Berry exchange coordinate{"} geometry.",

keywords = "3-Methyl-2-hydroxycyclopenten-2-one tin compounds, Berry exchange coordinate geometry, Penta- and hexacoordinated tin derivatives",

author = "Carlos Camacho-Camacho and Jim{\'e}nez-P{\'e}rez, {Victor M.} and Galvez-Ruiz, {Juan Carlos} and Angelina Flores-Parra and Rosalinda Contreras",

note = "Funding Information: Financial support from Cinvestav, Conacyt and UAM-X is acknowledged. ",

year = "2006",

month = apr,

day = "1",

doi = "10.1016/j.jorganchem.2005.12.036",

language = "Ingl{\'e}s",

volume = "691",

pages = "1590--1597",

journal = "Journal of Organometallic Chemistry",

issn = "0022-328X",

publisher = "Elsevier",

number = "8",

}

TY - JOUR

T1 - Berry exchange coordinate geometry in 3-methyl-2-hydroxycyclopenten-1-one tin esters

AU - Camacho-Camacho, Carlos

AU - Jiménez-Pérez, Victor M.

AU - Galvez-Ruiz, Juan Carlos

AU - Flores-Parra, Angelina

AU - Contreras, Rosalinda

N1 - Funding Information: Financial support from Cinvestav, Conacyt and UAM-X is acknowledged.

PY - 2006/4/1

Y1 - 2006/4/1

N2 - Three new penta- and hexacoordinated tin compounds (1-3) were prepared from PhSnCl3, Ph2SnCl2 and Ph3SnOH and 3-methyl-2-hydroxy-2-cyclopenten-1-one (L). Compounds 1-3 were characterized by IR, mass spectra, elemental analysis, 1H, 13C, and 119Sn NMR. The ligand acts as a bidentate giving the tin esters and coordinating the tin by the carbonyl group. Compound 1 (PhSnCl2L • EtOH) has an hexacoordinated tin atom, with an octahedral distorted geometry, which is a stereogenic center. Compounds 2 (Ph2SnClL) and 3 (Ph3SnL) have pentacoordinated tin atoms. The structures were determined by X-ray diffraction analyses. In the solid state 1 presents a racemic pair, linked by strong hydrogen bonds and 2 and 3 "Berry exchange coordinate" geometry.

AB - Three new penta- and hexacoordinated tin compounds (1-3) were prepared from PhSnCl3, Ph2SnCl2 and Ph3SnOH and 3-methyl-2-hydroxy-2-cyclopenten-1-one (L). Compounds 1-3 were characterized by IR, mass spectra, elemental analysis, 1H, 13C, and 119Sn NMR. The ligand acts as a bidentate giving the tin esters and coordinating the tin by the carbonyl group. Compound 1 (PhSnCl2L • EtOH) has an hexacoordinated tin atom, with an octahedral distorted geometry, which is a stereogenic center. Compounds 2 (Ph2SnClL) and 3 (Ph3SnL) have pentacoordinated tin atoms. The structures were determined by X-ray diffraction analyses. In the solid state 1 presents a racemic pair, linked by strong hydrogen bonds and 2 and 3 "Berry exchange coordinate" geometry.

KW - 3-Methyl-2-hydroxycyclopenten-2-one tin compounds

KW - Berry exchange coordinate geometry

KW - Penta- and hexacoordinated tin derivatives

UR - http://www.scopus.com/inward/record.url?scp=33644903794&partnerID=8YFLogxK

U2 - 10.1016/j.jorganchem.2005.12.036

DO - 10.1016/j.jorganchem.2005.12.036

M3 - Artículo

SN - 0022-328X

VL - 691

SP - 1590

EP - 1597

JO - Journal of Organometallic Chemistry

JF - Journal of Organometallic Chemistry

IS - 8

ER -

Berry exchange coordinate geometry in 3-methyl-2-hydroxycyclopenten-1-one tin esters

Abstract

Bibliographical note

Keywords

Access to Document

Other files and links

Fingerprint

Cite this