Isolation and characterization of luminescent bicyclic boronates based on furan ring-opening reactions from 5-formyl-2-furanboronic acid

Victoria E. González; Felipe Medrano; Mario Rodríguez; Pascal G. Lacroix; Victor Barba

doi:10.1016/j.tetlet.2014.09.033

Isolation and characterization of luminescent bicyclic boronates based on furan ring-opening reactions from 5-formyl-2-furanboronic acid

Victoria E. González, Felipe Medrano, Mario Rodríguez, Pascal G. Lacroix, Victor Barba^*

^*Corresponding author for this work

Departamento de Ciencias Químico-Biológicas

Research output: Contribution to journal › Article › peer-review

3 Scopus citations

Abstract

A new family of luminescent boronates was prepared from reaction of 5-formyl-2-furanboronic acid with 2-aminophenol derivatives. The furan ring-opening was favored by the presence of the boronic acid group. Evaluation of the photophysical characteristics for all compounds showed significant solvatochromic, fluorescent, and NLO properties.

Original language	English
Pages (from-to)	6088-6092
Number of pages	5
Journal	Tetrahedron Letters
Volume	55
Issue number	44
DOIs	https://doi.org/10.1016/j.tetlet.2014.09.033
State	Published - 29 Oct 2014

Bibliographical note

Funding Information:
This work was supported by the Consejo Nacional de Ciencia y Tecnología , México ( CB-2010/157743 ).

Publisher Copyright:
© 2014 Elsevier Ltd. All rights reserved.

Keywords

Boronic acid
Furan ring-opening
Luminescence
NLO properties
Solvatochromic effect

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10.1016/j.tetlet.2014.09.033

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AU - González, Victoria E.

AU - Medrano, Felipe

AU - Rodríguez, Mario

AU - Lacroix, Pascal G.

AU - Barba, Victor

PY - 2014/10/29

Y1 - 2014/10/29

N2 - A new family of luminescent boronates was prepared from reaction of 5-formyl-2-furanboronic acid with 2-aminophenol derivatives. The furan ring-opening was favored by the presence of the boronic acid group. Evaluation of the photophysical characteristics for all compounds showed significant solvatochromic, fluorescent, and NLO properties.

AB - A new family of luminescent boronates was prepared from reaction of 5-formyl-2-furanboronic acid with 2-aminophenol derivatives. The furan ring-opening was favored by the presence of the boronic acid group. Evaluation of the photophysical characteristics for all compounds showed significant solvatochromic, fluorescent, and NLO properties.

KW - Boronic acid

KW - Furan ring-opening

KW - Luminescence

KW - NLO properties

KW - Solvatochromic effect

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DO - 10.1016/j.tetlet.2014.09.033

M3 - Artículo

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EP - 6092

JO - Tetrahedron Letters

JF - Tetrahedron Letters

SN - 0040-4039

IS - 44

ER -

Isolation and characterization of luminescent bicyclic boronates based on furan ring-opening reactions from 5-formyl-2-furanboronic acid

Abstract

Bibliographical note

Keywords

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