Abstract
The temperature shift of the F absorption band for KBr and KC1 single crystals was experimentally and theoretically determined. The theoretical calculations are based on the pseudopotential method using different wave functions and assumed a linear thermal expansion coefficient for the crystalline lattice. The change of F-center absorption energy due to collisions with the thermally vibrating lattice is calculated. This contribution is small. The measurements agree fairly well with the results obtained using the present model.
Original language | English |
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Pages (from-to) | 101-110 |
Number of pages | 10 |
Journal | Radiation Effects and Defects in Solids |
Volume | 127 |
Issue number | 1 |
DOIs | |
State | Published - 1993 |
Bibliographical note
Funding Information:We are very grateful to Mr Ricardo Guerrero from IFUNAM, Mexico, for growing the crystals, Margarita Atondo who performed the additive coloration and Prof. A. Clark for useful discussions. This work was partially supported by Direccidn General de Investigacidn Cientifica y Superacidn Academica of the Secretaria de Educacidn Pdblica grant No. C89-07-0202, and Consejo Nacional de Ciencia y Tecnologia, grant No. P228CCOX-89-17-66.
Keywords
- defects in crystals
- impurity and defect absorption in solids
- impurity and defect levels