PbSe films by ion exchange of synthetic plumbonacrite layers immersed in a selenium ionic solution

T. Mendívil-Reynoso; R. Ochoa-Landín; L. P. Ramírez-Rodríguez; K. Gutierrez-Acosta; R. Ramírez-Bon; S. J. Castillo

doi:10.1016/j.jcrysgro.2016.03.002

PbSe films by ion exchange of synthetic plumbonacrite layers immersed in a selenium ionic solution

T. Mendívil-Reynoso, R. Ochoa-Landín, L. P. Ramírez-Rodríguez^*, K. Gutierrez-Acosta, R. Ramírez-Bon, S. J. Castillo

^*Corresponding author for this work

Research output: Contribution to journal › Article › peer-review

8 Scopus citations

Abstract

Plumbonacrite is a lead compound with chemical formula Pb₁₀(CO₃)₆(OH)_6O, where several groups can be substituted by ion exchange in mild conditions. Plumbonacrite layers can be deposited by means of the chemical bath deposition technique. In this work it is studied the structural and morphological evolution of a plumbonacrite layer as a function of the immersion time in an aqueous solution containing Se^-2 ions. The 1.39 μm thick plumbonacrite layer was chemically deposited on a glass substrate and immersed in an aqueous solution with Se^-2 ions for 10, 20, 30 and 50 min. The as grown plumbonacrite layer as well as the immersed ones were analyzed by X-rays Diffraction, Scanning Electron Microscopy and Raman Spectroscopy measurements. The results show that the plumbonacrite layer is gradually converted to PbSe one by ion exchange process, where Se^-2 ions substitute the groups of plumbonacrite.

Original language	English
Pages (from-to)	20-24
Number of pages	5
Journal	Journal of Crystal Growth
Volume	443
DOIs	https://doi.org/10.1016/j.jcrysgro.2016.03.002
State	Published - 1 Jun 2016

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© 2016 Elsevier B.V. All rights reserved.

Keywords

A1. Characterization
A1. Crystal morphology
A1. Crystal structure
B2. Semiconductor lead compound

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10.1016/j.jcrysgro.2016.03.002

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title = "PbSe films by ion exchange of synthetic plumbonacrite layers immersed in a selenium ionic solution",

abstract = "Plumbonacrite is a lead compound with chemical formula Pb10(CO3)6(OH)6O, where several groups can be substituted by ion exchange in mild conditions. Plumbonacrite layers can be deposited by means of the chemical bath deposition technique. In this work it is studied the structural and morphological evolution of a plumbonacrite layer as a function of the immersion time in an aqueous solution containing Se-2 ions. The 1.39 μm thick plumbonacrite layer was chemically deposited on a glass substrate and immersed in an aqueous solution with Se-2 ions for 10, 20, 30 and 50 min. The as grown plumbonacrite layer as well as the immersed ones were analyzed by X-rays Diffraction, Scanning Electron Microscopy and Raman Spectroscopy measurements. The results show that the plumbonacrite layer is gradually converted to PbSe one by ion exchange process, where Se-2 ions substitute the groups of plumbonacrite.",

keywords = "A1. Characterization, A1. Crystal morphology, A1. Crystal structure, B2. Semiconductor lead compound",

author = "T. Mend{\'i}vil-Reynoso and R. Ochoa-Land{\'i}n and Ram{\'i}rez-Rodr{\'i}guez, {L. P.} and K. Gutierrez-Acosta and R. Ram{\'i}rez-Bon and Castillo, {S. J.}",

year = "2016",

month = jun,

day = "1",

doi = "10.1016/j.jcrysgro.2016.03.002",

language = "Ingl{\'e}s",

volume = "443",

pages = "20--24",

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TY - JOUR

T1 - PbSe films by ion exchange of synthetic plumbonacrite layers immersed in a selenium ionic solution

AU - Mendívil-Reynoso, T.

AU - Ochoa-Landín, R.

AU - Ramírez-Rodríguez, L. P.

AU - Gutierrez-Acosta, K.

AU - Ramírez-Bon, R.

AU - Castillo, S. J.

PY - 2016/6/1

Y1 - 2016/6/1

N2 - Plumbonacrite is a lead compound with chemical formula Pb10(CO3)6(OH)6O, where several groups can be substituted by ion exchange in mild conditions. Plumbonacrite layers can be deposited by means of the chemical bath deposition technique. In this work it is studied the structural and morphological evolution of a plumbonacrite layer as a function of the immersion time in an aqueous solution containing Se-2 ions. The 1.39 μm thick plumbonacrite layer was chemically deposited on a glass substrate and immersed in an aqueous solution with Se-2 ions for 10, 20, 30 and 50 min. The as grown plumbonacrite layer as well as the immersed ones were analyzed by X-rays Diffraction, Scanning Electron Microscopy and Raman Spectroscopy measurements. The results show that the plumbonacrite layer is gradually converted to PbSe one by ion exchange process, where Se-2 ions substitute the groups of plumbonacrite.

AB - Plumbonacrite is a lead compound with chemical formula Pb10(CO3)6(OH)6O, where several groups can be substituted by ion exchange in mild conditions. Plumbonacrite layers can be deposited by means of the chemical bath deposition technique. In this work it is studied the structural and morphological evolution of a plumbonacrite layer as a function of the immersion time in an aqueous solution containing Se-2 ions. The 1.39 μm thick plumbonacrite layer was chemically deposited on a glass substrate and immersed in an aqueous solution with Se-2 ions for 10, 20, 30 and 50 min. The as grown plumbonacrite layer as well as the immersed ones were analyzed by X-rays Diffraction, Scanning Electron Microscopy and Raman Spectroscopy measurements. The results show that the plumbonacrite layer is gradually converted to PbSe one by ion exchange process, where Se-2 ions substitute the groups of plumbonacrite.

KW - A1. Characterization

KW - A1. Crystal morphology

KW - A1. Crystal structure

KW - B2. Semiconductor lead compound

UR - http://www.scopus.com/inward/record.url?scp=84962298254&partnerID=8YFLogxK

U2 - 10.1016/j.jcrysgro.2016.03.002

DO - 10.1016/j.jcrysgro.2016.03.002

M3 - Artículo

SN - 0022-0248

VL - 443

SP - 20

EP - 24

JO - Journal of Crystal Growth

JF - Journal of Crystal Growth

ER -

PbSe films by ion exchange of synthetic plumbonacrite layers immersed in a selenium ionic solution

Abstract

Bibliographical note

Keywords

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