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Photochemical syntheses of fullerene-amine adducts and their characterization with 1H NMR spectroscopy

  • Motomichi Inoue*
  • , Lorena Machi
  • , Francisco Brown
  • , Michiko B. Inoue
  • , Quintus Fernando
  • *Corresponding author for this work

Research output: Contribution to journalArticlepeer-review

Abstract

Photoreactions of C60 with aromatic or aliphatic amines in contact with air gave a new type of amine adduct with a general compound formula of C60(amine)x(OH)yOz; the amine was di-2-pyridylamine, morpholine or N,N-dimethylethylenediamine. The N,N-dimethylethylenediamine adduct was obtained as a hydrochloride. Its 1H NMR spectrum showed that the adduct cation, obtained after functionalizing C60, formed an ion pair with a benzenesulfonate anion.

Original languageEnglish
Pages (from-to)113-117
Number of pages5
JournalJournal of Molecular Structure
Volume345
DOIs
StatePublished - 1995

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