Polyaniline salts of toluenesulfonate and sulfonated poly(p-vinylphenol)

M. Inoue; F. Medrano; M.M. Castillo-Ortega; K. Asano; M. Nakamura

doi:https://doi.org/10.1016/0379-6779(93)90199-7

Polyaniline salts of toluenesulfonate and sulfonated poly(p-vinylphenol)

M. Inoue, F. Medrano, M.M. Castillo-Ortega, K. Asano, M. Nakamura

Research output: Contribution to journal › Article › peer-review

Abstract

Polyaniline salts of toluenesulfonate (TS) and sulfonated poly(p-vinylphenol) (SPVP) have been prepared. The polyaniline salt of TS exhibited a room-temperature electrical conductivity of 10 S cm−1. The activation energy for electrical conduction was 0.02 eV, which was significantly smaller than the value 0.04 eV reported for other salts. The aromatic nature of the organic anion is expected to enhance the interchain diffusion of charge carriers. The electrical conductivity of the polyaniline salt of the polymer anion was of the order of 10−4 S cm−1. A polyaniline base derived from the SPVP salt was water-soluble in the presence of excess NaSPVP, due to complexation between the two polymers.

Original language	Undefined/Unknown
Pages (from-to)	1057 - 1061
Journal	Synthetic Metals
Volume	55
Issue number	2
DOIs	https://doi.org/10.1016/0379-6779(93)90199-7
State	Published - 1993

Bibliographical note

Proceedings of the International Conference on Science and Technology of Synthetic Metals

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https://doi.org/10.1016/0379-6779(93)90199-7

http://www.sciencedirect.com/science/article/pii/0379677993901997

Cite this

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title = "Polyaniline salts of toluenesulfonate and sulfonated poly(p-vinylphenol)",

abstract = "Polyaniline salts of toluenesulfonate (TS) and sulfonated poly(p-vinylphenol) (SPVP) have been prepared. The polyaniline salt of TS exhibited a room-temperature electrical conductivity of 10 S cm−1. The activation energy for electrical conduction was 0.02 eV, which was significantly smaller than the value 0.04 eV reported for other salts. The aromatic nature of the organic anion is expected to enhance the interchain diffusion of charge carriers. The electrical conductivity of the polyaniline salt of the polymer anion was of the order of 10−4 S cm−1. A polyaniline base derived from the SPVP salt was water-soluble in the presence of excess NaSPVP, due to complexation between the two polymers.",

author = "M. Inoue and F. Medrano and M.M. Castillo-Ortega and K. Asano and M. Nakamura",

note = "Proceedings of the International Conference on Science and Technology of Synthetic Metals",

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TY - JOUR

T1 - Polyaniline salts of toluenesulfonate and sulfonated poly(p-vinylphenol)

AU - Inoue, M.

AU - Medrano, F.

AU - Castillo-Ortega, M.M.

AU - Asano, K.

AU - Nakamura, M.

N1 - Proceedings of the International Conference on Science and Technology of Synthetic Metals

PY - 1993

Y1 - 1993

N2 - Polyaniline salts of toluenesulfonate (TS) and sulfonated poly(p-vinylphenol) (SPVP) have been prepared. The polyaniline salt of TS exhibited a room-temperature electrical conductivity of 10 S cm−1. The activation energy for electrical conduction was 0.02 eV, which was significantly smaller than the value 0.04 eV reported for other salts. The aromatic nature of the organic anion is expected to enhance the interchain diffusion of charge carriers. The electrical conductivity of the polyaniline salt of the polymer anion was of the order of 10−4 S cm−1. A polyaniline base derived from the SPVP salt was water-soluble in the presence of excess NaSPVP, due to complexation between the two polymers.

AB - Polyaniline salts of toluenesulfonate (TS) and sulfonated poly(p-vinylphenol) (SPVP) have been prepared. The polyaniline salt of TS exhibited a room-temperature electrical conductivity of 10 S cm−1. The activation energy for electrical conduction was 0.02 eV, which was significantly smaller than the value 0.04 eV reported for other salts. The aromatic nature of the organic anion is expected to enhance the interchain diffusion of charge carriers. The electrical conductivity of the polyaniline salt of the polymer anion was of the order of 10−4 S cm−1. A polyaniline base derived from the SPVP salt was water-soluble in the presence of excess NaSPVP, due to complexation between the two polymers.

U2 - https://doi.org/10.1016/0379-6779(93)90199-7

DO - https://doi.org/10.1016/0379-6779(93)90199-7

M3 - Artículo

SN - 0379-6779

VL - 55

SP - 1057

EP - 1061

JO - Synthetic Metals

JF - Synthetic Metals

IS - 2

ER -