Polymerization of anilines by the use of copper(II) perchlorate as an oxidative coupling agent

Motomichi Inoue; Francisco Brown; Iliana C. Muñoz; Fca Ofelia Muñoz

doi:10.1007/BF00302607

Polymerization of anilines by the use of copper(II) perchlorate as an oxidative coupling agent

Motomichi Inoue^*, Francisco Brown, Iliana C. Muñoz, Fca Ofelia Muñoz

^*Corresponding author for this work

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Abstract

Polyaniline and polyalkylaniline perchlorates were prepared by oxidative coupling polymerization of anilines by the use of copper(II) perchlorate in acetonitrile as an oxidant. The corresponding polymer bases obtained by treating the perchlorates with alkaline solution were soluble in dimethylsulfoxide and partly soluble in tetrahydrofuran. The molecular weights of the THF-soluble components were 2000-6000. The charge transport of the perchlorates is influenced by the chain length and the steric effect of alkyl substituents.

Original language	English
Pages (from-to)	403-408
Number of pages	6
Journal	Polymer Bulletin
Volume	26
Issue number	4
DOIs	https://doi.org/10.1007/BF00302607
State	Published - Aug 1991

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title = "Polymerization of anilines by the use of copper(II) perchlorate as an oxidative coupling agent",

abstract = "Polyaniline and polyalkylaniline perchlorates were prepared by oxidative coupling polymerization of anilines by the use of copper(II) perchlorate in acetonitrile as an oxidant. The corresponding polymer bases obtained by treating the perchlorates with alkaline solution were soluble in dimethylsulfoxide and partly soluble in tetrahydrofuran. The molecular weights of the THF-soluble components were 2000-6000. The charge transport of the perchlorates is influenced by the chain length and the steric effect of alkyl substituents.",

author = "Motomichi Inoue and Francisco Brown and Mu{\~n}oz, {Iliana C.} and Mu{\~n}oz, {Fca Ofelia}",

year = "1991",

month = aug,

doi = "10.1007/BF00302607",

language = "Ingl{\'e}s",

volume = "26",

pages = "403--408",

journal = "Polymer Bulletin",

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TY - JOUR

T1 - Polymerization of anilines by the use of copper(II) perchlorate as an oxidative coupling agent

AU - Inoue, Motomichi

AU - Brown, Francisco

AU - Muñoz, Iliana C.

AU - Muñoz, Fca Ofelia

PY - 1991/8

Y1 - 1991/8

N2 - Polyaniline and polyalkylaniline perchlorates were prepared by oxidative coupling polymerization of anilines by the use of copper(II) perchlorate in acetonitrile as an oxidant. The corresponding polymer bases obtained by treating the perchlorates with alkaline solution were soluble in dimethylsulfoxide and partly soluble in tetrahydrofuran. The molecular weights of the THF-soluble components were 2000-6000. The charge transport of the perchlorates is influenced by the chain length and the steric effect of alkyl substituents.

AB - Polyaniline and polyalkylaniline perchlorates were prepared by oxidative coupling polymerization of anilines by the use of copper(II) perchlorate in acetonitrile as an oxidant. The corresponding polymer bases obtained by treating the perchlorates with alkaline solution were soluble in dimethylsulfoxide and partly soluble in tetrahydrofuran. The molecular weights of the THF-soluble components were 2000-6000. The charge transport of the perchlorates is influenced by the chain length and the steric effect of alkyl substituents.

UR - http://www.scopus.com/inward/record.url?scp=0026202424&partnerID=8YFLogxK

U2 - 10.1007/BF00302607

DO - 10.1007/BF00302607

M3 - Artículo

SN - 0170-0839

VL - 26

SP - 403

EP - 408

JO - Polymer Bulletin

JF - Polymer Bulletin

IS - 4

ER -

Polymerization of anilines by the use of copper(II) perchlorate as an oxidative coupling agent

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