TY - JOUR
T1 - Studies on diacetylenic vinyl compounds. II. Copolymerization of phenyl‐4′‐vinylphenylbutadiyne with styrene and methyl methacrylate
AU - Castillóan, Felipe F.
AU - Navarro, Rosa E.
AU - Ogawa, Takeshi
PY - 1988/1
Y1 - 1988/1
N2 - The copolymerizations of phenyl‐4′‐vinylphenylbutadiyne (PVPB) with styrene and methyl methacrylate were carried out under various conditions. PVPB was more readily incorporated in copolymerization than the comonomers, but the diacetylenic group of PVPB interacted with the propagating radical, decreasing the polymerization rate and the molecular weight of copolymer. When the polymerization system became very viscous, crosslinking took place giving light green luminescent gels. The thermal behaviors of copolymers were also studied.
AB - The copolymerizations of phenyl‐4′‐vinylphenylbutadiyne (PVPB) with styrene and methyl methacrylate were carried out under various conditions. PVPB was more readily incorporated in copolymerization than the comonomers, but the diacetylenic group of PVPB interacted with the propagating radical, decreasing the polymerization rate and the molecular weight of copolymer. When the polymerization system became very viscous, crosslinking took place giving light green luminescent gels. The thermal behaviors of copolymers were also studied.
UR - http://www.scopus.com/inward/record.url?scp=0023825502&partnerID=8YFLogxK
U2 - 10.1002/pola.1988.080260131
DO - 10.1002/pola.1988.080260131
M3 - Artículo
SN - 0887-624X
VL - 26
SP - 321
EP - 327
JO - Journal of Polymer Science Part A: Polymer Chemistry
JF - Journal of Polymer Science Part A: Polymer Chemistry
IS - 1
ER -