Unconventional hydrogen and dihydrogen bonded supramolecular array of a 2,6-dioxa-9,16-diaza-1,3(1,2),4(1,4)-tribenzenacycloheptadecaphane-borane adduct

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Abstract

The crystal structure of the title borane-oxaazacyclophane adduct consists of a tri-dimensional supramolecular array sustained by unconventional N-H⋯H-B and C-H⋯H-B dihydrogen bonding and weak C-H⋯π interactions. The interchain organization in the crystal structure is characterized by weak C-H⋯H-B dihydrogen bonds.

Original languageEnglish
Pages (from-to)115-123
Number of pages9
JournalArkivoc
Volume2008
Issue number5
DOIs
StatePublished - 2008

Keywords

  • Azacyclophane
  • Borane adduct
  • Dihydrogen bond
  • Supramolecular array
  • Unconventional bond

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