TY - JOUR
T1 - Density-temperature-softness scaling of the dynamics of glass-forming soft-sphere liquids
AU - Ramírez-González, Pedro E.
AU - López-Flores, Leticia
AU - Acuña-Campa, Heriberto
AU - Medina-Noyola, Magdaleno
PY - 2011/10/3
Y1 - 2011/10/3
N2 - We employ the principle of dynamic equivalence between soft-sphere and hard-sphere fluids to describe the interplay of the effects of varying the density n, the temperature T, and the softness (characterized by a softness parameter ν-1) on the dynamics of glass-forming soft-sphere liquids in terms of simple scaling rules. The main prediction is the existence of a dynamic universality class associated with the hard-sphere fluid, constituted by the soft-sphere systems whose dynamic parameters depend on n, T, and ν only through the reduced density n*nσ HS(T*,ν). A number of scaling properties observed in recent experiments and simulations involving glass-forming fluids with repulsive short-range interactions are found to be a direct manifestation of this general dynamic equivalence principle.
AB - We employ the principle of dynamic equivalence between soft-sphere and hard-sphere fluids to describe the interplay of the effects of varying the density n, the temperature T, and the softness (characterized by a softness parameter ν-1) on the dynamics of glass-forming soft-sphere liquids in terms of simple scaling rules. The main prediction is the existence of a dynamic universality class associated with the hard-sphere fluid, constituted by the soft-sphere systems whose dynamic parameters depend on n, T, and ν only through the reduced density n*nσ HS(T*,ν). A number of scaling properties observed in recent experiments and simulations involving glass-forming fluids with repulsive short-range interactions are found to be a direct manifestation of this general dynamic equivalence principle.
UR - http://www.scopus.com/inward/record.url?scp=80053463969&partnerID=8YFLogxK
U2 - 10.1103/PhysRevLett.107.155701
DO - 10.1103/PhysRevLett.107.155701
M3 - Artículo
C2 - 22107301
SN - 0031-9007
VL - 107
JO - Physical Review Letters
JF - Physical Review Letters
IS - 15
M1 - 155701
ER -