TY - JOUR
T1 - l-Proline-sodium nitrate obtained from solvent drop grinding
AU - Hernández-Paredes, Javier
AU - Carrillo-Pesqueira, Francisco Javier
AU - Esparza-Ponce, Hilda E.
AU - Hernández-Negrete, Ofelia
AU - Alvarez-Ramos, Mario E.
PY - 2015/5/8
Y1 - 2015/5/8
N2 - © 2015 Elsevier Ltd. All rights reserved. Abstract l-Proline sodium nitrate was obtained by the solvent drop grinding (SDG) technique. The compound was characterized by X-ray powder diffraction (XRPD), infrared spectroscopy (FTIR) and thermal analysis (DSC/TGA). Additionally, the material was tested for second harmonic generation (SHG). XRPD confirmed the presence of a new phase with a 1:1 stoichiometry and its crystal structure was determined. The FTIR spectroscopy depicted accurately the molecular characteristics of the compound and the thermal analysis showed that the compound is stable below 160 C. Surprisingly, the compound displayed modest NLO properties which were strongly affected by its crystal packing features.
AB - © 2015 Elsevier Ltd. All rights reserved. Abstract l-Proline sodium nitrate was obtained by the solvent drop grinding (SDG) technique. The compound was characterized by X-ray powder diffraction (XRPD), infrared spectroscopy (FTIR) and thermal analysis (DSC/TGA). Additionally, the material was tested for second harmonic generation (SHG). XRPD confirmed the presence of a new phase with a 1:1 stoichiometry and its crystal structure was determined. The FTIR spectroscopy depicted accurately the molecular characteristics of the compound and the thermal analysis showed that the compound is stable below 160 C. Surprisingly, the compound displayed modest NLO properties which were strongly affected by its crystal packing features.
U2 - 10.1016/j.poly.2015.02.034
DO - 10.1016/j.poly.2015.02.034
M3 - Article
SP - 84
EP - 88
JO - Polyhedron
JF - Polyhedron
SN - 0277-5387
ER -