One-step chemical synthesis of doped polythiophene by use of copper(II) perchlorate as an oxidant

M. B. Inoue; E. F. Velazquez; M. Inoue

doi:10.1016/0379-6779(88)90260-3

One-step chemical synthesis of doped polythiophene by use of copper(II) perchlorate as an oxidant

M. B. Inoue, E. F. Velazquez, M. Inoue^*

^*Autor correspondiente de este trabajo

Departamento de Ciencias Químico-Biológicas

Producción científica: Contribución a una revista › Artículo › revisión exhaustiva

56 Citas (Scopus)

Resumen

A reaction of 2,2′-bithiophene with copper(II) perchlorate in acetonitrile achieved polymerization and doping in one step, and yielded polythiophenes, [(C₄H₂S)(ClO₄)_x·yH₂O]_n. The polymers with x ∼ 0.17 and y ∼ 0.3 exhibited a high electrical conductivity in the range 3 - 8 S cm^-1 at 300 K and a small activation energy of 0.04 eV. The i.r. and e.s.r. spectra showed the characteristics of doped polythiophenes.

Idioma original	Inglés
Páginas (desde-hasta)	223-229
Número de páginas	7
Publicación	Synthetic Metals
Volumen	24
N.º	3
DOI	https://doi.org/10.1016/0379-6779(88)90260-3
Estado	Publicada - may. 1988

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title = "One-step chemical synthesis of doped polythiophene by use of copper(II) perchlorate as an oxidant",

abstract = "A reaction of 2,2′-bithiophene with copper(II) perchlorate in acetonitrile achieved polymerization and doping in one step, and yielded polythiophenes, [(C4H2S)(ClO4)x·yH2O]n. The polymers with x ∼ 0.17 and y ∼ 0.3 exhibited a high electrical conductivity in the range 3 - 8 S cm-1 at 300 K and a small activation energy of 0.04 eV. The i.r. and e.s.r. spectra showed the characteristics of doped polythiophenes.",

author = "Inoue, {M. B.} and Velazquez, {E. F.} and M. Inoue",

year = "1988",

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doi = "10.1016/0379-6779(88)90260-3",

language = "Ingl{\'e}s",

volume = "24",

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journal = "Synthetic Metals",

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TY - JOUR

T1 - One-step chemical synthesis of doped polythiophene by use of copper(II) perchlorate as an oxidant

AU - Inoue, M. B.

AU - Velazquez, E. F.

AU - Inoue, M.

PY - 1988/5

Y1 - 1988/5

N2 - A reaction of 2,2′-bithiophene with copper(II) perchlorate in acetonitrile achieved polymerization and doping in one step, and yielded polythiophenes, [(C4H2S)(ClO4)x·yH2O]n. The polymers with x ∼ 0.17 and y ∼ 0.3 exhibited a high electrical conductivity in the range 3 - 8 S cm-1 at 300 K and a small activation energy of 0.04 eV. The i.r. and e.s.r. spectra showed the characteristics of doped polythiophenes.

AB - A reaction of 2,2′-bithiophene with copper(II) perchlorate in acetonitrile achieved polymerization and doping in one step, and yielded polythiophenes, [(C4H2S)(ClO4)x·yH2O]n. The polymers with x ∼ 0.17 and y ∼ 0.3 exhibited a high electrical conductivity in the range 3 - 8 S cm-1 at 300 K and a small activation energy of 0.04 eV. The i.r. and e.s.r. spectra showed the characteristics of doped polythiophenes.

UR - http://www.scopus.com/inward/record.url?scp=0024016355&partnerID=8YFLogxK

U2 - 10.1016/0379-6779(88)90260-3

DO - 10.1016/0379-6779(88)90260-3

M3 - Artículo

AN - SCOPUS:0024016355

SN - 0379-6779

VL - 24

SP - 223

EP - 229

JO - Synthetic Metals

JF - Synthetic Metals

IS - 3

ER -

One-step chemical synthesis of doped polythiophene by use of copper(II) perchlorate as an oxidant

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